Design, Synthesis, Characterization, and Catalytic Properties of a Large-Pore Metal-Organic Framework Possessing Single-Site Vanadyl(monocatecholate) Moieties
نویسندگان
چکیده
Through a combination of protecting groups, postsynthesis deprotection, and postsynthesis metallation, a homogeneously inaccess ible , s ingle-s i te vanadyl(monocatecholate) moiety can be incorporated into the dipyridyl struts of a Zn-based, pillared paddlewheel MOF. The resulting MOF, which has large pores, exhibits catalytic activity in the benzylic oxidation of tetralin in the presence of tert-butylhydroperoxide.
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